Hydroalkoxylation Catalyzed by a Gold(I) Complex Encapsulated in a Supramolecular Host

被引：183
作者：
Wang, Z. Jane
Brown, Casey J.
Bergman, Robert G. [1 ]
Raymond, Kenneth N.
Toste, F. Dean
机构：
[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 19期
关键词：
AZA-COPE REARRANGEMENT; H BOND ACTIVATION; INTERMOLECULAR HYDROALKOXYLATION; ALLENES; GUEST; REACTIVITY; MECHANISM; SCOPE;
D O I：
10.1021/ja202055v
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Gold(I)-phosphine complexes are readily encapsulated by a tetrahedral supramolecular host (Ga4L6). We have investigated the catalytic activity of the resulting complexes for the intramolecular hydroalkoxylation of allenes. The catalytic activity of Me3PAuBr was increased 8-fold by encapsulation, as determined by initial rate kinetics, and we observed up to 67 catalytic turnovers by Me3PAu+ encapsulated in Ga4L6.
引用
收藏
页码：7358 / 7360
页数：3
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