Low temperature sintering and microwave dielectric properties of CoZrNb2O8 ceramics with H3BO3 addition

被引：9

作者：

Bi, J. X. ^{[1
]}

Xing, C. F. ^{[1
]}

Jiang, X. S. ^{[1
]}

Yang, C. H. ^{[1
]}

Wu, H. T. ^{[1
]}

机构：

[1] Univ Jinan, Sch Mat Sci & Engn, Jinan 250022, Peoples R China

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2016年 / 27卷 / 06期

关键词：

CRYSTAL-STRUCTURE; MN; MG; CO; PERMITTIVITY; AZRNB(2)O(8); REFINEMENT; BEHAVIOR; B2O3; ZN;

D O I：

10.1007/s10854-016-4601-7

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

The effects of H3BO3 additive on the sintering behavior, phase composition, microstructure and microwave dielectric properties of CoZrNb2O8 ceramics were investigated based on the research of pure-phase CoZrNb2O8 (CZN) ceramics. When 2.5 wt% H3BO3 was added to CoZrNb2O8 ceramics, the sintering temperatures significantly decreased from 1250 to 1200 degrees C due to the formation of liquid phase. The ceramic sintered at 1200 degrees C for 4 h exhibited excellent microwave dielectric properties of epsilon(r) = 21.62, Q.f = 40,200 GHz and tau(f) = -16.38 ppm/degrees C. Compared to the results of CZN ceramics, the H3BO3 additives effectively lowered the sintering temperature of CZN ceramics due to the liquid phase effect without detrimental effect on the properties.

引用

页码：6564 / 6569

页数：6

共 29 条

[11] Low permittivity SrCuSi4O10-LMZBS glass composite for LTCC applications [J].

Manu, K. M. ;

Anjana, P. S. ;

Sebastian, M. T. .

MATERIALS LETTERS, 2011, 65 (03) :565-567

[12] Structure and microwave dielectric properties of Ca0.66La0.387Ti0.88O3 ceramics [J].

Muhammad, Raz ;

Iqbal, Yaseen .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2015, 26 (11) :9092-9096

[13] Functional advances of microwave dielectrics for next generation [J].

Ohsato, Hitoshi .

CERAMICS INTERNATIONAL, 2012, 38 :S141-S146

[14] BA2TI9O20 AS A MICROWAVE DIELECTRIC RESONATOR [J].

PLOURDE, JK ;

LINN, DF ;

OBRYAN, HM ;

THOMSON, J .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1975, 58 (9-10) :418-420

[15] Structural, Raman spectroscopic and microwave dielectric studies on Ni1-x(Zn1/2Zr1/2)xW1-xNbxO4 ceramic compounds with wolframite structure [J].

Ramarao, S. D. ;

Murthy, V. R. K. .

DALTON TRANSACTIONS, 2015, 44 (05) :2311-2324

[16] Crystal structure refinement and microwave dielectric properties of new low dielectric loss AZrNb2O8 (A: Mn, Zn, Mg and Co) ceramics [J].

Ramarao, S. D. ;

Murthy, V. R. K. .

SCRIPTA MATERIALIA, 2013, 69 (03) :274-277

[17] Microwave dielectric ceramics for resonators and filters in mobile phone networks [J].

Reaney, Ian M. ;

Iddles, David .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (07) :2063-2072

[18] A PROFILE REFINEMENT METHOD FOR NUCLEAR AND MAGNETIC STRUCTURES [J].

RIETVELD, HM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1969, 2 :65-&

[19] Low loss dielectric materials for LTCC applications: a review [J].

Sebastian, M. T. ;

Jantunen, H. .

INTERNATIONAL MATERIALS REVIEWS, 2008, 53 (02) :57-90

[20] DIELECTRIC POLARIZABILITIES OF IONS IN OXIDES AND FLUORIDES [J].

SHANNON, RD .

JOURNAL OF APPLIED PHYSICS, 1993, 73 (01) :348-366

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