1D lanthanide halide crystals inserted into single-walled carbon nanotubes

被引:77
作者
Xu, CG
Sloan, J
Brown, G
Bailey, S
Williams, VC
Friedrichs, S
Coleman, KS
Flahaut, E
Hutchison, JL
Dunin-Borkowski, RE
Green, MLH
机构
[1] Univ Oxford, Wolfson Catalysis Ctr, Carbon Nanotechnol Grp, Inorgan Chem Lab, Oxford OX1 3QR, England
[2] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
关键词
D O I
10.1039/b006817i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
1D crystals of lanthanide halides of the form LnCl(3) (Ln = La, Nd, Sm, Eu, Gd, Tb or Yb) have been inserted into single-walled carbon nanotubes (SWNTs) using the molten salt capillary filling method; ca. 20-40% of all the observed SWNTs were filled with melts in the range 650-910 degreesC with no observable damage to the carbon tubules; high resolution transmission electron microscopy (HRTEM) studies showed that the nanostructures of the encapsulated crystals varied with tubule diameter.
引用
收藏
页码:2427 / 2428
页数:2
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