Metal-supported and -assisted stereoselective cooperative photoredox catalysis

被引：15

作者：

Busch, Jasmin ^{[1
]}

Knoll, Daniel M. ^{[1
]}

Zippel, Christoph ^{[1
]}

Braese, Stefan ^{[1
,2
]}

Bizzarri, Claudia ^{[1
]}

机构：

[1] Inst Organ Chem, Fritz Haber Weg 6, D-76131 Karlsruhe, Germany

[2] Inst Toxicol & Genet, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 41期

关键词：

VISIBLE-LIGHT PHOTOREDOX; LEWIS-ACID CATALYSIS; SINGLE-ELECTRON TRANSMETALATION; TRANSFER RADICAL-ADDITION; H BOND FUNCTIONALIZATION; C-H; MERGING PHOTOREDOX; NICKEL CATALYSIS; DUAL-CATALYSIS; DECARBOXYLATIVE ARYLATION;

D O I：

10.1039/c9dt02094b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this perspective, we review those stereoselective photocatalytic reactions that use synergy between photoredox catalysts and transition metal catalysts. In particular, we highlight the orchestrated interaction between two and more metals which not only enhance the turnover numbers, but also lead to increased selectivities. Aspects of green chemistry and sustainable developments are included. In this review, C-C, C-O, C-N and C-S forming reactions are discussed and a perspective on future developments is given.

引用

页码：15338 / 15357

页数：20

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