Recent Developments in the Nitroxide-Catalyzed Oxidation of Amines: Preparation of Imines and Nitriles

被引：29

作者：

Bartelson, Ashley L. ^{[1
]}

Lambert, Kyle M. ^{[2
]}

Bobbitt, James M. ^{[2
]}

Bailey, William F. ^{[2
]}

机构：

[1] Seton Hill Univ, Div Nat & Hlth Sci, 1 Seton Hill Dr, Greensburg, PA 15601 USA

[2] Univ Connecticut, Dept Chem, 55 North Eagleville Rd, Storrs, CT 06269 USA

来源：

CHEMCATCHEM | 2016年 / 8卷 / 22期

关键词：

amine oxidations; imines; nitriles; synthetic methods; tempo; AEROBIC OXIDATION; ELECTROCATALYTIC OXIDATION; MEDIATED ELECTROOXIDATION; RUTHENIUM HYDROXIDE; EFFICIENT CATALYST; SECONDARY-AMINES; DEHYDROGENATION; ALCOHOLS; COMPLEXES; BENZYLAMINES;

D O I：

10.1002/cctc.201600858

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This Concept highlights the discovery and developments in the oxidations of amines catalyzed by TEMPO (2,2,6,6-tetramethylpiperidinyl- N-oxyl) and related catalytic systems. The most important feature of these systems is that, with slight modifications in the reaction media, amines are selectively oxidized to either an imine or nitrile. Progress made toward the oxidation of various benzylic, allylic, and aliphatic amines, and possible reaction mechanism pathways are discussed.

引用

页码：3421 / 3430

页数：10

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