From nanoparticles to on-chip 3D nanothermite: electrospray deposition of reactive Al/CuO@NC onto semiconductor bridge and its application for rapid ignition

Nanothermites composed of nano-fuels and oxidants are attractive energetic materials, which have potential applications in microscale energy-demanding systems. Herein, nano-Al/CuO with nitrocellulose (NC) binder have been bottom-up assembled on semiconductor bridge (SCB) chip by electrospray, from nanoparticles to three-dimensional (3D) deposited structure. The morphological and compositional characterization confirms the constituents in Al/CuO@NC are homogeneously mixed at nano scale and the 3D structure at micro scale is tunable. The as-deposited Al/CuO@NC exhibits excellent energy output and superior chemical reactivity. Specifically, the heat release of Al/CuO@NC (1179.5 J g(-1)) is higher than that of random mixed Al/CuO (730.9 J g(-1)). Benefiting from outstanding exothermic properties, the material integrated with SCB initiator chip (Al/CuO@NC-SCB) for potential ignition application was investigated. The Al/CuO@NC-SCB micro energetic initiator can be functioned rapidly (with delay time of 2.8 mu s) and exhibits superb ignition performances with violent explosion process, high combustion temperature (4636 degrees C) and successful ignition of B/KNO3 propellant, in comparison to SCB initiator. The strategy provides promising route to introduce nano reactive particles into various functional energy-demanding systems for potential energetic applications.