KOtBu mediated efficient approach for the synthesis of fused heterocycles via intramolecular O-/N-arylations

被引：33
作者：
Singha, Raju [1 ]
Ahmed, Atiur [1 ]
Nuree, Yasin [1 ]
Ghosh, Munmun [1 ]
Ray, Jayanta K. [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India
来源：
RSC ADVANCES | 2015年 / 5卷 / 62期
关键词：
AMINATION REACTIONS; C-N; LACTONIZATION; CARBAZOLES; BUTOXIDE; LIGANDS; ROUTE; BONDS; AIR;
D O I：
10.1039/c5ra07532g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel and efficient methodology for the synthesis of 6H-benzo[c]chromenes, 6H-benzo[c]chromen-6-ones, carbazoles, dibenzofurans, dibenzooxepins has been developed. The reaction goes through intramolecular O-/N-arylations with sp(2)C-Br bonds via typical SNAr pathway in presence of potassium-tert-butoxide base.
引用
收藏
页码：50174 / 50177
页数：4
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