Titanium-mediated addition of diallylsilanes to oxalyl chloride: formation of a diquinane

被引：1
|
作者：
Aouf, Chahinez [1 ]
El Abed, Douniazad [1 ]
Giorgi, Michel [2 ]
Santelli, Maurice [1 ]
机构：
[1] Aix Marseille Univ, CNRS, UMR 6263, Organ Synth Lab, F-13397 Marseille 20, France
[2] Aix Marseille Univ, Fac Sci St Jerome, F-13397 Marseille 20, France
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 24期
关键词：
acylation; oxalyl chloride; diallylsilane; titanium tetrachloride;
D O I：
10.1016/j.tetlet.2008.04.078
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The titanium tetrachloride mediated reaction of the cis, cis-2,6-dimethyl-1, 8-bis(trimethylsilyl)-2,6-octadiene with oxalyl chloride yielded 1-hydroxy-4-methyl-8-(1-propen-2-yl)bicyclo[3.3.0]oct-3-en-2-one of which the structure was confirmed by X-ray crystallographic analysis. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3862 / 3864
页数：3
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