(EDT-TTF-I2)2PbI3•H2O:: an ambient pressure metal with a β′ donor slab topology

被引：34

作者：

Devic, T

Canadell, E

Auban-Senzier, P

Batail, P

机构：

[1] Univ Angers, Lab Chim Inorgan Mat & Interfaces, CNRS, FRE 2447, F-49045 Angers, France

[2] CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain

[3] Univ Paris 11, Phys Solides Lab, CNRS, UMR 8502, F-91405 Orsay, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2004年 / 14卷 / 02期

关键词：

D O I：

10.1039/b312493b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Water molecules are interspersed within ribbons of face-sharing [PbI6/2-](infinity) octahedra within the title hybrid phase in which the stacks of organic radical cations are less strongly dimerised and interact more with each other than is usually the case in beta' phases to achieve metallic conductivity at ambient pressure.

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页码：135 / 137

页数：3

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