Synthesis and structure of the cobalt(II) coordination compounds with N,N-dimethyl-N',N'-dimethylthiocarbamoylsulfenamide

被引：1

作者：

Khitrich, G. N. ^{[1
]}

Seifullin, I. I. ^{[1
]}

Khitrich, N. V. ^{[1
]}

机构：

[1] Mechnikov Odessa Natl Univ, UA-65082 Odessa, Ukraine

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2011年 / 81卷 / 05期

关键词：

General Chemistry; Electron Absorption Spectrum; Coordination Compound; Diffuse Reflectance Spectrum; Thioamide;

D O I：

10.1134/S1070363211050070

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The CoLX2 complexes were obtained by the reaction of N,N-dimethyl-N',N'-dimethylthio-carbamoylsulfenamide (L) with CoX2 (X = Cl, Br, I, NCS). The complexes were investigated by elemental and X-ray analysis, IR, H-1 NMR, and electron spectroscopy, conductometry, magnetochemistry, thermogravimetry. It is found that these compounds are high-spin complexes of pseudotetraedral structure with bidentate coordination of L through the thione sulfur atom and sulfenamide nitrogen atom.

引用

页码：840 / 844

页数：5

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