Synthesis and structure of the cobalt(II) coordination compounds with N,N-dimethyl-N',N'-dimethylthiocarbamoylsulfenamide

被引：1
|
作者：
Khitrich, G. N. [1 ]
Seifullin, I. I. [1 ]
Khitrich, N. V. [1 ]
机构：
[1] Mechnikov Odessa Natl Univ, UA-65082 Odessa, Ukraine
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2011年 / 81卷 / 05期
关键词：
General Chemistry; Electron Absorption Spectrum; Coordination Compound; Diffuse Reflectance Spectrum; Thioamide;
D O I：
10.1134/S1070363211050070
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The CoLX2 complexes were obtained by the reaction of N,N-dimethyl-N',N'-dimethylthio-carbamoylsulfenamide (L) with CoX2 (X = Cl, Br, I, NCS). The complexes were investigated by elemental and X-ray analysis, IR, H-1 NMR, and electron spectroscopy, conductometry, magnetochemistry, thermogravimetry. It is found that these compounds are high-spin complexes of pseudotetraedral structure with bidentate coordination of L through the thione sulfur atom and sulfenamide nitrogen atom.
引用
收藏
页码：840 / 844
页数：5
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