Tetraethylammonium bromo(1,3-dithiol-2-one-4,5-dithiolato)diethylstannate(1-)

被引:8
作者
Chohan, ZH
Wardell, JL
Low, JN
Meehan, PR
Ferguson, G
机构
[1] Univ Aberdeen, Dept Chem, Old Aberdeen AB24 3UE, Scotland
[2] Univ Dundee, Dept Appl Phys & Elect & Mech Engn, Dundee DD1 4HN, Scotland
[3] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada
关键词
D O I
10.1107/S0108270198006027
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, tetraethylammonium bromo[4,5-dimercapto-1,3-dithiol-2-onato(2-)-S-4,S-5]diethylstannate(1-), [N(C2H5)(4)] [SnBr(C2H5)(2)(C3OS4)], the anion lies about a mirror plane and the Sn atom has distorted trigonal-bipyramidal geometry, with axial distances Sn-Br 2.8776(16) and Sn-S 2.562(2)Angstrom, and equatorial distances Sn-S 2.458(2) and Sn-C 2.111(7) Angstrom. The [NEt4](+) cation is disordered about an inversion centre.
引用
收藏
页码:1401 / 1403
页数:3
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