Tetraethylammonium bromo(1,3-dithiol-2-one-4,5-dithiolato)diethylstannate(1-)

被引：7
作者：
Chohan, ZH
Wardell, JL
Low, JN
Meehan, PR
Ferguson, G
机构：
[1] Univ Aberdeen, Dept Chem, Old Aberdeen AB24 3UE, Scotland
[2] Univ Dundee, Dept Appl Phys & Elect & Mech Engn, Dundee DD1 4HN, Scotland
[3] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷
关键词：
D O I：
10.1107/S0108270198006027
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, tetraethylammonium bromo[4,5-dimercapto-1,3-dithiol-2-onato(2-)-S-4,S-5]diethylstannate(1-), [N(C2H5)(4)] [SnBr(C2H5)(2)(C3OS4)], the anion lies about a mirror plane and the Sn atom has distorted trigonal-bipyramidal geometry, with axial distances Sn-Br 2.8776(16) and Sn-S 2.562(2)Angstrom, and equatorial distances Sn-S 2.458(2) and Sn-C 2.111(7) Angstrom. The [NEt4](+) cation is disordered about an inversion centre.
引用
收藏
页码：1401 / 1403
页数：3
相关论文
共 23 条
  • [1] Allen F.H., 1993, CHEM AUTOMAT NEWS, V8, P31
  • [2] AUPERS JH, 1998, IN PRESS POLYHEDRON
  • [3] Preparations and crystal structures of Sn(CH(2)CH(2)CO(2)Me)(2)(C3S5) and [Q][Sn(CH(2)CH(2)CO(2)Me)(C3S5)(2)] (Q=NEt(4) or 1,4-dimethylpyridinium, C3S5=4,5-disulfanyl-1,3-dithiole-2-thionate)
    Buchanan, H
    Howie, RA
    Khan, A
    Spencer, GM
    Wardell, JL
    Aupers, JH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (04): : 541 - 548
  • [4] Synthesis of bis[(ferrocenylmethyl)trimethylammonium] [bis(1,3-dithiole-2-thione-4,5-dithiolato)zincate] and [bis(1,3-dithiole-2-one-4,5-dithiolato)zincate] salts, ([FcCH(2)NMe(3)](2)[Zn(dmit)(2)] and [FcCH(2)NMe(3)](2)[Zn(dmio)(2)]): Crystal structures of [FcCH(2)NMe(3)](2)[Zn(dmit)(2)] and [NEt4](2)[Zn(dmit)(2)]center dot MeOH
    Chohan, ZH
    Howie, RA
    Wardell, JL
    Wilkens, R
    DoidgeHarrison, SMSV
    [J]. POLYHEDRON, 1997, 16 (15) : 2689 - 2696
  • [5] DOIDGEHARRISON SMS, 1992, J ORGANOMET CHEM, V463, P23
  • [6] Diorganotin 1,3-dithiole-2-thione-4,5-dithiolate compounds, R(2)Sn(dmit): The crystal structure of MePhSn(dmit)
    DoidgeHarrison, SMSV
    Irvine, JTS
    Khan, A
    Spencer, GM
    Wardell, JL
    Aupers, JH
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 516 (1-2) : 199 - 205
  • [7] DOIDGEHARRISON SMSV, 1991, J ORGANOMET CHEM, V414, pC5, DOI 10.1016/0022-328X(91)83250-8
  • [8] DOIDGEHARRISON SMSV, 1992, POLYHEDRON, V11, P2223, DOI 10.1016/S0277-5387(00)83700-6
  • [9] ENRAFNONIUS, 1992, CAD 4 PC SOFTWARE VE
  • [10] FERGUSON G, 1997, PRPCIF97 WORDPERFECT
123