A Novel Diruthenium Acetylide Donor Complex as an Unusual Active Material for Bulk Heterojunction Solar Cells

被引:26
作者
Colombo, Alessia [1 ,2 ]
Dragonetti, Claudia [1 ,2 ]
Roberto, Dominique [1 ,2 ,3 ]
Ugo, Renato [1 ,2 ,3 ]
Falciola, Luigi [4 ]
Luzzati, Silvia [5 ]
Kotowski, Dariusz [5 ]
机构
[1] Univ Milan, Dipartimento CIMA L Malatesta, I-20133 Milan, Italy
[2] UdR INSTM Milano, I-20133 Milan, Italy
[3] CNR, ISTM, I-20133 Milan, Italy
[4] Univ Milan, Dipartimento Chim Fis & Elettrochim, I-20133 Milan, Italy
[5] CNR, ISMAC, I-20133 Milan, Italy
关键词
PHOTOVOLTAIC CELLS; CONVERSION EFFICIENCY; CONJUGATED POLYMERS; ENERGY-CONVERSION; ELECTRON-TRANSFER; CHARGE-TRANSPORT; POLY(ARYLENEETHYNYLENE)S; PHOTOCURRENT; PERFORMANCE; ABSORPTION;
D O I
10.1021/om100846e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new dinuclear Ru(II) complex where two Ru atoms are separated by a bridge consisting of a 2,1,3-benzothiadiazole acceptor moiety flanked on either side by 2,5-thienyl donor units was synthesized. This rather simple complex appears to behave as a photoactive donor when blended with a fullerene as acceptor, thus being a first step toward novel bulk heterojunction solar cells, based on Ru donor systems.
引用
收藏
页码:1279 / 1282
页数:4
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