Characterisation of aquatic humic and non-humic matter with size-exclusion chromatography - organic carbon detection - organic nitrogen detection (LC-OCD-OND)

被引：1117
作者：
Huber, Stefan A. [1 ]
Balz, Andreas [1 ]
Abert, Michael [1 ]
Pronk, Wouter [2 ]
机构：
[1] DOC LABOR Dr Huber, D-76229 Karlsruhe, Germany
[2] Eawag, Swiss Fed Inst Aquat Sci & Technol, CH-8600 Dubendorf, Switzerland
来源：
WATER RESEARCH | 2011年 / 45卷 / 02期
关键词：
Humic substances; Fulvic acids; Humic acids; HS-diagram; Organic carbon detector; SEC; Nitrogen detector; Biopolymers; EfOM; SECONDARY EFFLUENT; MOLECULAR-WEIGHT; WATER; QUANTIFICATION; IDENTIFICATION; SUBSTANCES; ADSORPTION; SELECTION; FOULANTS; REMOVAL;
D O I：
10.1016/j.watres.2010.09.023
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Size-exclusion chromatography in combination with organic carbon detection (SEC-OCD) is an established method to separate the pool of NOM into major fractions of different sizes and chemical functions and to quantify these on the basis of organic carbon. One specific approach, also known as LC-OCD-OND, is based on the Grantzel thin-film UV-reactor. This approach is described with recent improvements in fraction assignation (humic substances, biopolymers, building blocks, low molecular weight organic acids and neutrals, hydrophobic organic carbon), the coupling of a novel organic nitrogen detector (OND), and an improved diagram for the characterisation of aquatic humic substances (HS-diagram). The diagram replaces the operational distinction between humic and fulvic acids by a continuum ranging from aquagenic fulvic acids to pedogenic humic acids. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：879 / 885
页数：7
相关论文
共 35 条
[11]   Removal of bulk dissolved organic carbon (DOC) and trace organic compounds by bank filtration and artificial recharge [J].
Grünheid, S ;
Amy, G ;
Jekel, M .
WATER RESEARCH, 2005, 39 (14) :3219-3228
[12]   Impact of coagulation and adsorption on DOC fractions of secondary effluent and resulting fouling behaviour in ultrafiltration [J].
Haberkamp, Jens ;
Ruhl, Aki S. ;
Ernst, Mathias ;
Jekel, Martin .
WATER RESEARCH, 2007, 41 (17) :3794-3802
[13]  
Heijboer R, 2006, POWER PLANT CHEM, V8, P197
[14]   Optimization of method for detecting and characterizing NOM by HPLC-size exclusion chromatography with UV and on-line DOC detection [J].
Her, N ;
Amy, G ;
Foss, D ;
Cho, J ;
Yoon, Y ;
Kosenka, P .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (05) :1069-1076
[15]   Variations of molecular weight estimation by HP-size exclusion chromatography with UVA versus online DOC detection [J].
Her, N ;
Amy, G ;
Foss, D ;
Cho, JW .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (15) :3393-3399
[16]  
Huber S.A., 1996, Vom Wasser, V86, P277
[17]   Evidence for membrane fouling by specific TOC constituents [J].
Huber, SA .
DESALINATION, 1998, 119 (1-3) :229-234
[18]   FLOW-INJECTION ANALYSIS OF ORGANIC AND INORGANIC CARBON IN THE LOW-PPB RANGE [J].
HUBER, SA ;
FRIMMEL, FH .
ANALYTICAL CHEMISTRY, 1991, 63 (19) :2122-2130
[19]   DIRECT GEL CHROMATOGRAPHIC CHARACTERIZATION AND QUANTIFICATION OF MARINE DISSOLVED ORGANIC-CARBON USING HIGH-SENSITIVITY DOC DETECTION [J].
HUBER, SA ;
FRIMMEL, FH .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1994, 28 (06) :1194-1197
[20]  
HUBER SA, 2005, P SEM PUR WAT CHEM 2, P75
1234