A photoelectron spectroscopic and computational study of the o-dicarbadodecaborane parent anion

被引：4

作者：

Zhang, Xinxing ^{[1
]}

Bowen, Kit ^{[1
]}

机构：

[1] Johns Hopkins Univ, Dept Chem, Charles & 34Th St, Baltimore, MD 21218 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 2016年 / 144卷 / 22期

关键词：

AB-INITIO; CARBORANES; ORGANOBORANES; SERIES; 1,2-DICARBACLOVODODECABORANE(12); REDUCTION; CHEMISTRY; FAMILY;

D O I：

10.1063/1.4953773

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report a combined photoelectron spectroscopic and computational study of the o-dicarbadodecaborane (o-carborane) parent anion, (C2B10H12)(-). Previous studies that focused on the electrophilic nature of o-carborane led to tantalizing yet mixed results. In our study, we confirmed that o-carborane does in fact form a parent anion and that it has considerable stability. This anion is an isomer ("Anion iso 2") where unlike in neutral o-carborane, the two carbon atoms are not bound. Published by AIP Publishing.

引用

页数：4

共 33 条

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