Self-assembled Pd nanoparticle-containing ionic liquid: Efficient and reusable catalyst for the Heck reaction in water

被引：8

作者：

Zong, Yingxiao ^{[1
,2
]}

Wang, Junke ^{[2
,4
]}

An, Pengli ^{[2
]}

Yue, Guoren ^{[2
]}

Pan, Yi ^{[3
]}

Wang, Xicun ^{[1
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Gansu Key Lab Polymer Mat, Lanzhou 730070, Gansu, Peoples R China

[2] Hexi Univ, Key Lab Hexi Corridor Resources Utilizat Gansu, Zhangye 734000, Peoples R China

[3] Nanjing Univ, Coll Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

[4] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2017年 / 31卷 / 11期

基金：

中国国家自然科学基金;

关键词：

C-C coupling; Heck reaction; ionic liquid; nanoparticle; palladium; CROSS-COUPLING REACTIONS; BISOXAZOLINE/PD COMPOSITE MICROSPHERE; PALLADIUM/IMIDAZOLIUM CHLORIDE SYSTEM; HIGHLY EFFICIENT; SUZUKI-MIYAURA; ARYL CHLORIDES; PALLADIUM NANOPARTICLES; RECYCLABLE CATALYST; COMPLEXES; LIGAND;

D O I：

10.1002/aoc.3762

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A self-assembled Pd nanoparticle-containing ionic liquid as metal-organic polymer was successfully prepared. The structure of the catalyst was characterized using Fourier transform infrared and H-1 NMR spectroscopies, scanning electron microscopy and elemental analysis. The catalyst was effectively employed in the palladium-catalyzed Heck reaction in water as a green solvent. Moreover, due to its stability the catalyst can be recovered simply and effectively and reused nine times without much loss of activity.

引用

页码：2389 / 2396

页数：8

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