Copper(II)-coordinated organic nanotube: A novel heterogeneous catalyst for various oxidation reactions

被引：28

作者：

Chattopadhyay, Tanmay ^{[1
]}

Kogiso, Masaki ^{[1
]}

Asakawa, Masumi ^{[1
]}

Shimizu, Toshimi ^{[1
]}

Aoyagi, Masaru ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Nanotube Res Ctr NTRC, Tsukuba, Ibaraki 3058565, Japan

来源：

CATALYSIS COMMUNICATIONS | 2010年 / 12卷 / 01期

关键词：

Copper(II)-coordinated organic nanotube; Heterogeneous catalyst; Oxidation of various organic compounds; Reusability; Peroxo bridge nano-intermediate; HYDROGEN-PEROXIDE; TRANSITION-METAL; LIPID NANOTUBES; ARCHITECTURES; COPPER(II); COMPLEXES; BONDS;

D O I：

10.1016/j.catcom.2010.07.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Copper(II)-coordinated organic nanotube can function as a heterogeneous catalyst for oxidation of a variety of organic compounds in the presence of hydrogen peroxide and tert-butyl hydroperoxide. The morphology of this catalyst remained same before and after the oxidation reactions. The catalyst can be reused for several times. In the presence of hydrogen peroxide, Copper(II)-coordinated organic nanotube formed a stable brown color peroxo bridge intermediate. But such intermediate did not form with tert-butyl hydroperoxide. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：9 / 13

页数：5

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