Synthesis and characterization of silver-nanoparticle-deposited α-Bi2Mo3O12 nanorods

被引：7

作者：

Ghule, Anil Vithal ^{[1
]}

Ghule, Kalyani ^{[1
]}

Tzing, Shin-Hwa ^{[1
]}

Ling, Yong-Chien ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 21卷 / 21期

关键词：

nanoparticles; ultrasound; deposition; nanorods; surface analysis; electron microscopy;

D O I：

10.1002/ejic.200700181

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver (Ag) nanoparticles with an average size of ca. 10 nm were uniformly deposited on the surface of alpha-Bi2Mo3O12 nanorods by using an ultrasound sonication method. Ultrasonic irradiation of preformed alpha-Bi2Mo3O12 spherical nanoparticles (ca. 200 nm) in pyridine resulted in alpha-Bi2Mo3O12 nanorods (ca. 100 nm diameter). Further, sonication of the mixture of alpha-Bi2Mo3O12 nanorods and Ag2O in pyridine yielded a nanocomposite of alpha-Bi2Mo3O12 nanorods with deposited Ag nanoparticles and pyridine. Calcination of the nanocomposite at 450 degrees C afforded pyridine-free alpha-Bi2Mo3O12 nanorods with deposited Ag nanoparticles. A plausible mechanism is proposed. The crystallized Ag nanoparticles are uniformly deposited on the surface, with bismuth (Bi) as the preferential binding site, as revealed by time-of-flight secondary ion mass spectrometry (TOF-SIMS). Structural, compositional and morphological characterization of the products is carried out by using transmission electron microscopy, energy-dispersive X-ray analysis, scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, Xray photoelectron spectroscopy and TOF-SIMS. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).

引用

页码：3342 / 3349

页数：8

共 50 条

[1] Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].

Alexandre, Michael ;

Dubois, Philippe .

Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63

[2]

[Anonymous], 1988, ULTRASOUND ITS CHEM, DOI DOI 10.1121/1.398864

[3] Surface aspects of bismuth-metal oxide catalysts [J].

Arora, N ;

Deo, G ;

Wachs, IE ;

Hirt, AM .

JOURNAL OF CATALYSIS, 1996, 159 (01) :1-13

[4] Synthesis and characterization of single-crystalline nanowires of bismuth doped with manganese [J].

Ban, ZH ;

He, JB ;

Golub, V ;

Wang, WD ;

O'Connor, CJ .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (12) :1244-1247

[5] Progress in the intercalation of pyridine and other organic bases into crystalline bismuth molybdenum oxide hydrate, BiMo2O7OH•2H2O [J].

Barnes, N ;

Kitchin, SJ ;

Hriljac, JA .

INORGANIC CHEMISTRY, 1999, 38 (26) :6317-+

[6] In situ study of the formation of crystalline bismuth molybdate materials under hydrothermal conditions [J].

Beale, AM ;

Sankar, G .

CHEMISTRY OF MATERIALS, 2003, 15 (01) :146-153

[7]

BOON L, 1990, EUR J SOL STATE INOR, V27, P381

[8] Static and in situ TEM investigation of phase relationships, phase dissolution, and interface motion in Ag-Au-Cu alloy nanoparticles [J].

Chatterjee, K ;

Howe, JM ;

Johnson, WC ;

Murayama, M .

ACTA MATERIALIA, 2004, 52 (10) :2923-2935

[9] Formation of highly ordered organic monolayers by dative bonding: Pyridine on Ge(100) [J].

Cho, YE ;

Maeng, JY ;

Kim, S ;

Hong, SY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (25) :7514-7515

[10] A general route to nanostructured bismuth chalcogenides [J].

Christian, P ;

O'Brien, P .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (29) :3021-3025

← 1 2 3 4 5 →