Some neutral ruthenium vinylidene complexes and a novel 1,3-elimination reaction: Preparation of chiral ruthenium acetylides

被引：41

作者：

Bruce, MI ^{[1
]}

Hall, BC ^{[1
]}

Zaitseva, NN ^{[1
]}

Skelton, BW ^{[1
]}

White, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 522卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

ruthenium; chirality; crystal structure; vinylidene;

D O I：

10.1016/0022-328X(96)06200-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of RuCl(PPh(3))(2)Cp* with 1-alkynes in non-polar solvents afford the neutral vinylidene complexes RuCl(C=CHR)(PPh(3))Cp* [R = Ph (X-ray structure), Bu(t), SiMe(3), CO(2)Me]; a novel 1,3 elimination of HCl induced by NaOMe in the presence of a variety of ligands gives the chiral-at-metal complexes Ru(C=CR)(L)(PPh(3))Cp* [L = CO, C2H4 (X-ray structure), PR(3), P(OR)(3), O-2, S-2, CS2 (for example)].

引用

页码：307 / 310

页数：4

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