Novel spinel oxide Li4/3Ti5/3O4 as electrochemical insertion materials for rechargeable lithium batteries

被引：27

作者：

Kanamura, K

Naito, H

Takehara, Z

机构：

[1] Dept. of Ener. and Hydrocarbon Chem., Graduate School of Engineering, Kyoto University, Kyoto 606-01, Sakyo-ku

来源：

CHEMISTRY LETTERS | 1997年 / 01期

关键词：

D O I：

10.1246/cl.1997.45

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We firstly claim that the unique performance of Li4/3Ti5/3O4 as electrochemical materials in terms of a flat potential and an infinitesimal structural change is caused by a cation ordering of Li+ and Ti4+ at 16d sites in the spinel superstructure.

引用

页码：45 / 46

页数：2

共 20 条

[1] STRUCTURE AND ELECTROCHEMISTRY OF THE SPINEL OXIDES LITI2O4 AND LI4/3TI5/3O4 [J].

COLBOW, KM ;

DAHN, JR ;

HAERING, RR .

JOURNAL OF POWER SOURCES, 1989, 26 (3-4) :397-402

[2] RECHARGEABLE LINIO2 CARBON CELLS [J].

DAHN, JR ;

VONSACKEN, U ;

JUZKOW, MW ;

ALJANABY, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (08) :2207-2211

[3] SPINEL ANODES FOR LITHIUM-ION BATTERIES [J].

FERG, E ;

GUMMOW, RJ ;

DEKOCK, A ;

THACKERAY, MM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) :L147-L150

[4] THE SUPERCONDUCTOR-SEMICONDUCTOR TRANSITION IN THE LI1+XTI2-XO4 SPINEL SYSTEM [J].

HARRISON, MR ;

EDWARDS, PP ;

GOODENOUGH, JB .

PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1985, 52 (03) :679-699

[5] Structural change of the LiMn2O4 spinel structure induced by extraction of lithium [J].

Kanamura, K ;

Naito, H ;

Yao, T ;

Takehara, Z .

JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (01) :33-36

[6]

KOSHIBA N, 1994, DENKI KAGAKU, V62, P970

[7]

KOSHIBA N, 1994, DENKI KAGAKU, V62, P870

[8]

Mosbah A., 1983, Materials Research Bulletin, V18, P1375, DOI 10.1016/0025-5408(83)90045-4

[9] ZERO-STRAIN INSERTION MATERIAL OF LI[LI1/3TI5/3]O-4 FOR RECHARGEABLE LITHIUM CELLS [J].

OHZUKU, T ;

UEDA, A ;

YAMAMOTO, N .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (05) :1431-1435

[10] ELECTROCHEMISTRY AND STRUCTURAL CHEMISTRY OF LINIO2 (R(3)OVER-BAR-M) FOR 4 VOLT SECONDARY LITHIUM CELLS [J].

OHZUKU, T ;

UEDA, A ;

NAGAYAMA, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (07) :1862-1870

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