Unusual heterometallic ZnMg(COO)3 building blocks for the construction of a homochiral srs-type metal-organic framework

被引：13
|
作者：
Yang, Hui [1 ,2 ]
Li, Tie-hu [1 ]
Wang, Fei [2 ]
Zhang, Jian [2 ]
机构：
[1] Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 35002, Fujian, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 16卷
关键词：
Metal-organic framework; Zinc; Topology; Chiral; Crystal structure; ZEOLITIC TOPOLOGIES; CHARGE-DISTRIBUTION; TEMPERATURE; CHEMISTRY; CLUSTERS; POLYMERS; PORES; NETS;
D O I：
10.1016/j.inoche.2011.11.039
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new homochiral metal-organic framework [ZnMg(btc)(H2O)(4)](NO3) (1, btc=1,3,5-benzenetricarboxylate) with unusual 3-connected heterometallic ZnMg(COO)(3) building blocks has been solvothermally synthesized and structurally characterized with the aid of single crystal X-ray diffraction. Compound 1 crystallizes in a chiral space group and exhibits 3-connected srs structural topology. The results reveal the first srs-type metal-organic framework constructed from heterometallic building blocks. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：86 / 88
页数：3
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