Unusual heterometallic ZnMg(COO)3 building blocks for the construction of a homochiral srs-type metal-organic framework

被引：13

作者：

Yang, Hui ^{[1
,2
]}

Li, Tie-hu ^{[1
]}

Wang, Fei ^{[2
]}

Zhang, Jian ^{[2
]}

机构：

[1] Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 35002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 16卷

关键词：

Metal-organic framework; Zinc; Topology; Chiral; Crystal structure; ZEOLITIC TOPOLOGIES; CHARGE-DISTRIBUTION; TEMPERATURE; CHEMISTRY; CLUSTERS; POLYMERS; PORES; NETS;

D O I：

10.1016/j.inoche.2011.11.039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new homochiral metal-organic framework [ZnMg(btc)(H2O)(4)](NO3) (1, btc=1,3,5-benzenetricarboxylate) with unusual 3-connected heterometallic ZnMg(COO)(3) building blocks has been solvothermally synthesized and structurally characterized with the aid of single crystal X-ray diffraction. Compound 1 crystallizes in a chiral space group and exhibits 3-connected srs structural topology. The results reveal the first srs-type metal-organic framework constructed from heterometallic building blocks. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：86 / 88

页数：3

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