Sprayed Cu2ZnSn(S,Se)4 Solar Cells with Controlled S/(S plus Se) Ratio

被引:1
作者
Choo, Chanho [1 ]
Lim, Dain [1 ]
Kim, Sunwoong [1 ]
Yoo, Hyesun [1 ]
Kim, Seongyeon [1 ]
Kim, Junho [1 ]
机构
[1] Incheon Natl Univ, Dept Phys, Incheon 22012, South Korea
基金
新加坡国家研究基金会;
关键词
CZTSSe; Solution Process; Spray Pyrolysis; Solar Cell; Band Gap Tuning; FABRICATION; CIGS;
D O I
10.1166/jno.2018.2401
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We fabricated Cu2ZnSn(S,Se)(4) absorber layers with different S/(S+ Se) ratios using spray pyrolysis and post sulfo-selenization. We found that the band gap was controlled by varying the S/(S + Se) ratio during the sulfo-selenization process. This was confirmed by Raman and UV-Vis spectroscopy. We fabricated solar cells and characterized their properties. The best cell efficiency was 3.62% when S/(S+ Se) = 0.46. The external quantum efficiency result also showed that the CZTSSe absorber was well-grown with a designed optical band gap.
引用
收藏
页码:1725 / 1728
页数:4
相关论文
共 14 条
[1]   Compositional dependence of structural and electronic properties of Cu2ZnSn(S,Se)4 alloys for thin film solar cells [J].
Chen, Shiyou ;
Walsh, Aron ;
Yang, Ji-Hui ;
Gong, X. G. ;
Sun, Lin ;
Yang, Ping-Xiong ;
Chu, Jun-Hao ;
Wei, Su-Huai .
PHYSICAL REVIEW B, 2011, 83 (12)
[2]   Combinatorial Exploration of the Effects of Intrinsic and Extrinsic Defects in Cu2ZnSn(S,Se)4 [J].
Collord, A. D. ;
Xin, H. ;
Hillhouse, H. W. .
IEEE JOURNAL OF PHOTOVOLTAICS, 2015, 5 (01) :288-298
[3]   Role of S and Se atoms on the microstructural properties of kesterite Cu2ZnSn(SxSe1-x)4 thin film solar cells [J].
Dimitrievska, Mirjana ;
Fairbrother, Andrew ;
Gunder, Rene ;
Gurieva, Galina ;
Xie, Haibing ;
Saucedo, Edgardo ;
Perez-Rodriguez, Alejandro ;
Izquierdo-Roca, Victor ;
Schorr, Susan .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (12) :8692-8700
[4]   Raman scattering quantitative analysis of the anion chemical composition in kesterite Cu2ZnSn(SxSe1-x)4 solid solutions [J].
Dimitrievska, Mirjana ;
Gurieva, Galina ;
Xie, Haibing ;
Carrete, Alex ;
Cabot, Andreu ;
Saucedo, Edgardo ;
Perez-Rodriguez, Alejandro ;
Schorr, Susan ;
Izquierdo-Roca, Victor .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 628 :464-470
[5]   Band alignment at the Cu2ZnSn(SxSe1-x)4/CdS interface [J].
Haight, Richard ;
Barkhouse, Aaron ;
Gunawan, Oki ;
Shin, Byungha ;
Copel, Matt ;
Hopstaken, Marinus ;
Mitzi, David B. .
APPLIED PHYSICS LETTERS, 2011, 98 (25)
[6]   Development of CZTS-based thin film solar cells [J].
Katagiri, Hironori ;
Jimbo, Kazuo ;
Maw, Win Shwe ;
Oishi, Koichiro ;
Yamazaki, Makoto ;
Araki, Hideaki ;
Takeuchi, Akiko .
THIN SOLID FILMS, 2009, 517 (07) :2455-2460
[7]   A Nonvacuum Approach for Fabrication of Cu2ZnSnSe4/In2S3 Thin Film Solar Cell and Optoelectronic Characterization [J].
Khadka, Dhruba B. ;
Kim, SeongYeon ;
Kim, JunHo .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (22) :12226-12235
[8]   Fabrication of CIGS thin films by using spray pyrolysis and post-selenization [J].
Kim, Seong Yeon ;
Kim, JunHo .
JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2012, 60 (12) :2018-2024
[9]   Effect of selenization on sprayed Cu2ZnSnSe4 thin film solar cell [J].
Kim, SeongYeon ;
Kim, JunHo .
THIN SOLID FILMS, 2013, 547 :178-180
[10]   Application of slope-polishing technique for depth profile of selenized CIGS by micro-Raman spectroscopy [J].
Kwon, Min-Su ;
Kang, Jeong-yoon ;
Kim, SeongYeon ;
Kim, JunHo ;
Jeon, Chan-Wook .
APPLIED SURFACE SCIENCE, 2016, 379 :186-190