Ambient Pressure Structural Quantum Critical Point in the Phase Diagram of (CaxSr1-x)3Rh4Sn13

被引:88
作者
Goh, S. K. [1 ,2 ]
Tompsett, D. A. [3 ]
Saines, P. J. [4 ]
Chang, H. C. [2 ]
Matsumoto, T. [5 ]
Imai, M. [5 ]
Yoshimura, K. [5 ]
Grosche, F. M. [2 ]
机构
[1] Chinese Univ Hong Kong, Dept Phys, Shatin, Hong Kong, Peoples R China
[2] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
[3] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[4] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England
[5] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan
基金
英国工程与自然科学研究理事会;
关键词
SUPERCONDUCTIVITY;
D O I
10.1103/PhysRevLett.114.097002
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The quasiskutterudite superconductor Sr3Rh4Sn13 features a pronounced anomaly in electrical resistivity at T* similar to 138 K. We show that the anomaly is caused by a second-order structural transition, which can be tuned to 0 K by applying physical pressure and chemical pressure via the substitution of Ca for Sr. A broad superconducting dome is centered around the structural quantum critical point. Detailed analysis of the tuning parameter dependence of T* as well as insights from lattice dynamics calculations strongly support the existence of a structural quantum critical point at ambient pressure when the fraction of Ca is 0.9 (i.e., x(c) = 0.9). This establishes the (CaxSr1-x)(3)Rh4Sn13 series as an important system for exploring the physics of structural quantum criticality without the need of applying high pressures.
引用
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页数:5
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