Molecular transition-metal phosphonates

被引：74

作者：

Chandrasekhar, Vadapalli ^{[1
]}

Senapati, Tapas ^{[1
]}

Dey, Atanu ^{[1
]}

Hossain, Sakiat ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 20期

关键词：

DODECANUCLEAR CHROMIUM(III) CAGE; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; COORDINATION CHEMISTRY; SINGLE-CRYSTAL; STRUCTURAL CHEMISTRY; ORGANIC FRAMEWORKS; 2,4,6-TRIISOPROPYLPHENYLPHOSPONIC ACID; ASYMMETRIC HYDROGENATION; SULFONATE-PHOSPHONATES;

D O I：

10.1039/c0dt01069c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Molecular transition-metal phosphonates are of relatively recent origin and can be assembled by several synthetic strategies. The nuclearity and the structure of the metal aggregates can be modulated by several factors including the stoichiometry of the reactants, nature of the metal precursor and the type of phosphonic acid used. This perspective summarizes some of the recent work carried out on copper(II)-, zinc(II)- and cadmium(II) phosphonates with particular emphasis on their synthesis and structure.

引用

页码：5394 / 5418

页数：25

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