Synthesis and structure of a new open metal-organic-inorganic hybrid framework [Sn(SO4)(BDC)(H2O)] (BDC = terephthalic acid)

被引：0

作者：

Sun, JY

Zhou, YM

Chen, ZX

Tu, B

Weng, LH

Zhao, DY ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Mol Catalysis & Innovate Mat Lab, Shanghai 200433, Peoples R China

[2] Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2003年 / 24卷 / 09期

关键词：

metal-organic framework; Sn complex; coordination polymer; synthesis; structure;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new coordination polymer [Sn (SO4) (BDC) (H2O)] (BDC = terephthalic acid) with two dimensional (2D) open metal-organic-inganic hybrid framework structure has solvothermally prepared in N, N-dimethylformamide solution at 160 degreesC. The structure determined from X-ray single crystal diffraction has space group P2(1) of monoclinic system with a=0.681 6(5), b=1. 762 8(14), c=0. 772 2(6) nm, beta=103 70 V=0.901 2(12) nm(3), Z=4, D-c=1.569 Mg/m(3); R-1=0.051 4[I > 2sigma(I)], R-w=0.1381. The product is characteristic of 2D channels with W wavy layer structure.

引用

页码：1555 / 1557

页数：3

共 10 条

[1] Organotin assemblies containing Sn-O bonds [J].