Structural, spectroscopic and magnetic properties of new copper(II) complexes with a terpyridine ligand

被引：29

作者：

Walesa-Chorab, Monika ^{[1
]}

Stefankiewicz, Artur R. ^{[1
,2
]}

Gorczynski, Adam ^{[1
]}

Kubicki, Maciej ^{[1
]}

Klak, Julia ^{[3
]}

Korabik, Maria J. ^{[3
]}

Patroniak, Violetta ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

[2] Univ Chem Lab, Cambridge CB2 1EW, England

[3] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

POLYHEDRON | 2011年 / 30卷 / 02期

关键词：

Coordination modes; Copper; Magnetic properties; ELECTRONIC-PROPERTIES; DNA-BINDING; CRYSTAL-STRUCTURES; METAL; STEREOCHEMISTRY; CHEMISTRY; CU(II); PHASE; IONS;

D O I：

10.1016/j.poly.2010.10.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four mononuclear complexes of the dimethylterpyridine ligand 1,3-bis(6-methylpyridin-2-yl)pyridine, L, C17H15N3, of the general formula CuLX2 were prepared from different copper(II) salts (X = Cl--1a, Br--1b, NO3--1c and ClO4--1d). Their properties have been characterized through analytical, spectroscopic (EPR, ESI-MS, and IR) and magnetic measurements. Single crystal X-ray structure analyses of these complexes revealed five-coordinate metal ions in 1a, 1b and 1c, whereas id turned out to contain a six-coordinate Cu(II) center and to have both unique magnetic and structural properties, rationalized in terms of the hydrogen-bonding interactions seen in its crystal lattice. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：233 / 240

页数：8

共 50 条

[31] Chemical and magnetic properties of the new copper(II) complexes with alkylaminoacetylureas
Ciurla, H., 1600, Elsevier Ltd (341): : 1 - 2
[32] Nickel(II), Cadmium(II), and Copper(II) Complexes Based on Ditopic Terpyridine Derivative Ligand: Syntheses, Crystal Structures, and Luminescent Properties
Zhang, Ai-Jiang
Chen, Chang-Juan
Lou, Dong-Yang
Miao, Yu-Hang
Qiao, Chen-Xu
Hu, Jiang-Bo
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2016, 642 (14): : 817 - 822
[33] Synthesis, structure, magnetism, and spectroscopic properties of heterobinuclear copper(II)-zinc(II) complexes and their copper(II)-copper(II) analogues in asymmetric ligand environments
Ghosh, D
Kundu, N
Maity, G
Choi, KY
Caneschi, A
Endo, A
Chaudhury, M
INORGANIC CHEMISTRY, 2004, 43 (19) : 6015 - 6023
[34] SYNTHETIC AND STRUCTURAL STUDIES ON COPPER(II) COMPLEXES CONTAINING COENZYME PQQ AND TERPYRIDINE
NAKAMURA, N
KOHZUMA, T
KUMA, H
SUZUKI, S
INORGANIC CHEMISTRY, 1994, 33 (08) : 1594 - 1599
[35] Synthesis, spectroscopic and magnetic properties of methoxo-bridged copper(II) complexes with 2-amino-4-methylpyridine as the ligand
Komaei, SA
van Albada, GA
Reedijk, J
TRANSITION METAL CHEMISTRY, 1999, 24 (01) : 104 - 107
[36] Synthesis, spectroscopic and magnetic properties of methoxo- bridged copper(II) complexes with 2-amino-4-methylpyridine as the ligand
Saeid Amani Komaei
Gerard A. van Albada
Jan Reedijk
Transition Metal Chemistry, 1999, 24 : 104 - 107
[37] Antiferromagnetic resorcinol bridged dinuclear square-planar copper (II) complexes: Syntheses, structural, spectroscopic and magnetic properties
Das, Manish
Bhunia, Pradip
Mukherjee, Ayan
Costa-Villen, Ernesto
Mayans, Julia
Guha, Pampa
INORGANICA CHIMICA ACTA, 2024, 569
[38] Mixed-ligand Copper(II) Complexes: Investigation of their Spectroscopic, Catalysis, Antimicrobial and Potentiometric Properties
Mehmet Tümer
Nihal Deligönül
Ayşegül Gölcü
Eyüp Akgün
Mustafa Dolaz
Havva Demirelli
Metin Dığrak
Transition Metal Chemistry, 2006, 31 : 1 - 12
[39] Mixed-ligand copper(II) complexes:: Investigation of their spectroscopic, catalysis, antimicrobial and potentiometric properties
Tümer, M
Deligönül, N
Gölcü, A
Akgün, E
Dolaz, M
Demirelli, H
Digrak, M
TRANSITION METAL CHEMISTRY, 2006, 31 (01) : 1 - 12
[40] SYNTHESIS, SPECTROSCOPIC AND MAGNETIC-PROPERTIES OF COPPER-COMPLEXES WITH A LIGAND CONTAINING PYRIDOXAL MOIETY
NARDELLI, M
PELIZZI, C
PREDIERI, G
TRANSITION METAL CHEMISTRY, 1978, 3 (04) : 233 - 236

← 1 2 3 4 5 →