Functionalization of graphene by electrophilic alkylation of reduced graphite

被引:60
作者
Englert, Jan M. [1 ,2 ]
Knirsch, Kathrin C. [1 ,2 ]
Dotzer, Christoph [1 ,2 ]
Butz, Benjamin [3 ]
Hauke, Frank [1 ,2 ]
Spiecker, Erdmann [3 ]
Hirsch, Andreas [1 ,2 ]
机构
[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91054 Erlangen, Germany
[2] Univ Erlangen Nurnberg, Inst Adv Mat & Proc ZMP, D-91054 Erlangen, Germany
[3] Univ Erlangen Nurnberg, Ctr Nanoanal & Electron Microscopy CENEM, Dept Mat Sci, D-91058 Erlangen, Germany
基金
欧洲研究理事会;
关键词
RAMAN-SPECTROSCOPY; CARBON NANOTUBES; DEFECTS; SHEETS;
D O I
10.1039/c2cc31181j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of Na/K-reduced graphite with hexyliodide represents a new, versatile and mild approach to synthesize alkylated graphene derivatives, which were characterized by a combination of Raman spectroscopy, TEM and TGA/MS analysis.
引用
收藏
页码:5025 / 5027
页数:3
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    Lomeda, Jay R.
    Doyle, Condell D.
    Kosynkin, Dmitry V.
    Hwang, Wen-Fang
    Tour, James M.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (48) : 16201 - 16206
  • [12] Quantifying ion-induced defects and Raman relaxation length in graphene
    Lucchese, M. M.
    Stavale, F.
    Ferreira, E. H. Martins
    Vilani, C.
    Moutinho, M. V. O.
    Capaz, Rodrigo B.
    Achete, C. A.
    Jorio, A.
    [J]. CARBON, 2010, 48 (05) : 1592 - 1597
  • [13] Towards Tunable Graphene/Phthalocyanine-PPV Hybrid Systems
    Malig, Jenny
    Jux, Norbert
    Kiessling, Daniel
    Cid, Juan-Jose
    Vazquez, Purificacion
    Torres, Tomas
    Guldi, Dirk M.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (15) : 3561 - 3565
  • [14] Electric field effect in atomically thin carbon films
    Novoselov, KS
    Geim, AK
    Morozov, SV
    Jiang, D
    Zhang, Y
    Dubonos, SV
    Grigorieva, IV
    Firsov, AA
    [J]. SCIENCE, 2004, 306 (5696) : 666 - 669
  • [15] Functionalization of Graphene via 1,3-Dipolar Cycloaddition
    Quintana, Mildred
    Spyrou, Konstantinos
    Grzelczak, Marek
    Browne, Wesley R.
    Rudolf, Petra
    Prato, Maurizio
    [J]. ACS NANO, 2010, 4 (06) : 3527 - 3533
  • [16] Solutions of Negatively Charged Graphene Sheets and Ribbons
    Valles, Cristina
    Drummond, Carlos
    Saadaoui, Hassan
    Furtado, Clascidia A.
    He, Maoshuai
    Roubeau, Olivier
    Ortolani, Luca
    Monthioux, Marc
    Penicaud, Alain
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (47) : 15802 - +