The mechanism of photoinduced hydrogen transfer during photoreduction of carbonyl compounds

被引:13
|
作者
Chesnokov, S. A. [1 ]
Shurygina, M. P. [1 ]
Abakumov, G. A. [1 ]
机构
[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
基金
俄罗斯基础研究基金会;
关键词
RADICAL-ION PAIR; ELECTRON-TRANSFER; PICOSECOND DYNAMICS; LASER PHOTOLYSIS; BENZOPHENONE; COMPLEX;
D O I
10.1134/S0018143911040059
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A model reaction of hydrogen transfer has been proposed that describes well the results of kinetic studies of the photoreduction of o- and p-quinones and fluorenone in the presence of para-substituted N,N-dimethylanilines and polyalkylbenzenes in various solvents.
引用
收藏
页码:287 / 299
页数:13
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