The mechanism of photoinduced hydrogen transfer during photoreduction of carbonyl compounds

被引:13
|
作者
Chesnokov, S. A. [1 ]
Shurygina, M. P. [1 ]
Abakumov, G. A. [1 ]
机构
[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
基金
俄罗斯基础研究基金会;
关键词
RADICAL-ION PAIR; ELECTRON-TRANSFER; PICOSECOND DYNAMICS; LASER PHOTOLYSIS; BENZOPHENONE; COMPLEX;
D O I
10.1134/S0018143911040059
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A model reaction of hydrogen transfer has been proposed that describes well the results of kinetic studies of the photoreduction of o- and p-quinones and fluorenone in the presence of para-substituted N,N-dimethylanilines and polyalkylbenzenes in various solvents.
引用
收藏
页码:287 / 299
页数:13
相关论文
共 50 条
  • [21] One-pot Reductive Amination of carbonyl Compounds with Nitro Compounds by Transfer Hydrogenation over Co-Nx as catalyst
    Zhou, Peng
    Zhang, Zehui
    CHEMSUSCHEM, 2017, 10 (09) : 1892 - 1897
  • [22] Mechanism for Fluorescence Quenching of Tryptophan by Oxamate and Pyruvate: Conjugation and Solvation-Induced Photoinduced Electron Transfer
    Peng, Huo-Lei
    Callender, Robert
    JOURNAL OF PHYSICAL CHEMISTRY B, 2018, 122 (25): : 6483 - 6490
  • [23] Kinetics and mechanism of catalytic oxidation of alcohols to carbonyl compounds with dioxygen in the Pd-containing aqua system
    V. V. Potekhin
    Russian Chemical Bulletin, 2007, 56 : 875 - 882
  • [24] Photoinduced electron transfer between multifunctional porphyrin and ubiquinone analogues linked by several hydrogen-bonding interactions
    Hayashi, T
    Miyahara, T
    Kumazaki, S
    Ogoshi, H
    Yoshihara, K
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (17): : 1964 - 1966
  • [25] On the Role of Hydrogen Bonds in Photoinduced Electron-Transfer Dynamics between 9-Fluorenone and Amine Solvents
    Ghosh, Hirendra N.
    Adamczyk, Katrin
    Verma, Sandeep
    Dreyer, Jens
    Nibbering, Erik T. J.
    CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (16) : 4930 - 4937
  • [26] Verification of the electron/proton coupled mechanism for phenolic H-atom transfer using a triplet π,π* carbonyl
    Yamaji, Minoru
    Oshima, Juro
    Hidaka, Motohiko
    CHEMICAL PHYSICS LETTERS, 2009, 475 (4-6) : 235 - 239
  • [27] Photoinduced Iron(III)-Mediated Atom Transfer Radical Polymerization with In Situ Generated Initiator: Mechanism and Kinetics Studies
    Zhou, Yin-Ning
    Guo, Jun-Kang
    Li, Jin-Jin
    Luo, Zheng-Hong
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2016, 55 (39) : 10235 - 10242
  • [28] General and Efficient a-Oxygenation of Carbonyl Compounds by TEMPO Induced by Single-Electron-Transfer Oxidation of Their Enolates
    Dinca, Emanuela
    Hartmann, Philip
    Smrcek, Jakub
    Dix, Ina
    Jones, Peter G.
    Jahn, Ullrich
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 2012 (24) : 4461 - 4482
  • [29] Mechanism of Alkene Hydrofunctionalization by Oxidative Cobalt(salen) Catalyzed Hydrogen Atom Transfer
    Wilson, Conner V.
    Holland, Patrick L.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (04) : 2685 - 2700
  • [30] Influences of protonation and hydrogen bonding on intramolecular charge transfer compounds possessing different spacers
    Wang, Shun-Li
    Lin, Ju-Mei
    Shu, Shiang-En
    Chern, Ching-Yuh
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2010, 210 (01) : 54 - 60