The inhibition effect of Azure A on mild steel in 1 M HCl. A complete study: Adsorption, temperature, duration and quantum chemical aspects

被引:86
作者
Ozkir, Demet [1 ]
Kayakirilmaz, Kadriye [1 ]
Bayol, Emel [1 ]
Gurten, A. Ali [2 ]
Kandemirli, Fatma [1 ]
机构
[1] Nigde Univ, Fac Arts & Sci, Dept Chem, TR-51100 Nigde, Turkey
[2] Osmaniye Korkut Ata Univ, Fac Arts & Sci, Dept Chem, TR-80000 Osmaniye, Turkey
关键词
Mild steel; EIS; SEM; Modeling studies; Acid corrosion; SULFURIC-ACID; CORROSION INHIBITION; CARBON-STEEL; TRIAZOLE DERIVATIVES; SCHIFF-BASE; WEIGHT-LOSS; BEHAVIOR; POLARIZATION; POLYANILINE; CHEMISTRY;
D O I
10.1016/j.corsci.2011.11.010
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, inhibition effect of Azure A on mild steel in 1.0 M HCl were evaluated by using electrochemical impedance spectroscopy (EIS), linear polarization resistance (LPR), and potentiodynamic polarization and scanning electron microscope (SEM) methods. These studies were carried out at different concentrations, temperatures and durations. The inhibitor molecules were chemisorbed on electrode surface according to the Langmuir adsorption isotherm. The quantum chemical calculations were employed to give further insight into the inhibition mechanism of Azure A. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:143 / 152
页数:10
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