Facile access to B-doped solid-state fluorescent carbon dots toward light emitting devices and cell imaging agents

被引:118
作者
Shen, Chen [1 ]
Wang, Jing [1 ]
Cao, Yi [1 ]
Lu, Yun [1 ]
机构
[1] Nanjing Univ, Dept Polymer Sci & Engn, State Key Lab Coordinat Chem,Minist Educ,Sch Chem, Collaborat Innovat Ctr Chem Life Sci,Key Lab High, Nanjing 210093, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
GRAPHENE QUANTUM DOTS; PHOTOCATALYTIC ACTIVITY; SURFACE-STATES; LOW-COST; NANODOTS; NANOPARTICLES; LUMINESCENCE; ROUTE; PHOTOLUMINESCENCE; SPHERES;
D O I
10.1039/c5tc01156f
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A green and facile hydrothermal approach for carbonizing boric acid and ethylenediamine into B-doped carbon dots (CDs) has been proposed, providing a new method to synthesize functional carbon dots on a large scale. The obtained B-doped CDs exhibit favorable aqueous solubility and strong fluorescence in both aqueous and solid states. Especially, the unique solid-state fluorescence properties of the B-doped CDs inspire new thoughts for other applications, accordingly a yellowish-green light emitting diode with the as-obtained CDs as light converters is demonstrated. Meanwhile, the as-prepared CDs also display intensely low toxicity and excellent multicolour fluorescence imaging ability in live cells.
引用
收藏
页码:6668 / 6675
页数:8
相关论文
共 51 条
  • [1] Luminescent Carbon Nanodots: Emergent Nanolights
    Baker, Sheila N.
    Baker, Gary A.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (38) : 6726 - 6744
  • [2] Electrochemical Tuning of Luminescent Carbon Nanodots: From Preparation to Luminescence Mechanism
    Bao, Lei
    Zhang, Zhi-Ling
    Tian, Zhi-Quan
    Zhang, Li
    Liu, Cui
    Lin, Yi
    Qi, Baoping
    Pang, Dai-Wen
    [J]. ADVANCED MATERIALS, 2011, 23 (48) : 5801 - 5806
  • [3] Photophysical Properties of Doped Carbon Dots (N, P, and B) and Their Influence on Electron/Hole Transfer in Carbon Dots-Nickel (II) Phthalocyanine Conjugates
    Barman, Monoj Kumar
    Jana, Bikash
    Bhattacharyya, Santanu
    Patra, Amitava
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (34) : 20034 - 20041
  • [4] Mass production and dynamic imaging of fluorescent nanodiamonds
    Chang, Yi-Ren
    Lee, Hsu-Yang
    Chen, Kowa
    Chang, Chun-Chieh
    Tsai, Dung-Sheng
    Fu, Chi-Cheng
    Lim, Tsong-Shin
    Tzeng, Yan-Kai
    Fang, Chia-Yi
    Han, Chau-Chung
    Chang, Huan-Cheng
    Fann, Wunshain
    [J]. NATURE NANOTECHNOLOGY, 2008, 3 (05) : 284 - 288
  • [5] Choi H, 2013, NAT PHOTONICS, V7, P732, DOI [10.1038/nphoton.2013.181, 10.1038/NPHOTON.2013.181]
  • [6] Environment-dependent photon emission from solid state carbon dots and its mechanism
    Deng, Yehao
    Chen, Xing
    Wang, Fei
    Zhang, Xueao
    Zhao, Dongxu
    Shen, Dezhen
    [J]. NANOSCALE, 2014, 6 (17) : 10388 - 10393
  • [7] Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid
    Dong, Yongqiang
    Shao, Jingwei
    Chen, Congqiang
    Li, Hao
    Wang, Ruixue
    Chi, Yuwu
    Lin, Xiaomei
    Chen, Guonan
    [J]. CARBON, 2012, 50 (12) : 4738 - 4743
  • [8] A green one-arrow-two-hawks strategy for nitrogen-doped carbon dots as fluorescent ink and oxygen reduction electrocatalysts
    Gao, Shuyan
    Chen, Yanli
    Fan, Hao
    Wei, Xianjun
    Hu, Chuangang
    Wang, Lixia
    Qu, Liangti
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (18) : 6320 - 6325
  • [9] Hg(II) sensing based on functionalized carbon dots obtained by direct laser ablation
    Goncalves, Helena
    Jorge, Pedro A. S.
    Fernandes, J. R. A.
    Esteves da Silva, Joaquim C. G.
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2010, 145 (02) : 702 - 707
  • [10] Fluorescent carbon nanoparticles for the fluorescent detection of metal ions
    Guo, Yongming
    Zhang, Lianfeng
    Zhang, Shushen
    Yang, Yan
    Chen, Xihan
    Zhang, Mingchao
    [J]. BIOSENSORS & BIOELECTRONICS, 2015, 63 : 61 - 71