A rational synthetic route leading to 3d-3d′-4f heterospin systems:: self-assembly processes involving heterobinuclear 3d-4f complexes and hexacyanometallates

被引：149

作者：

Gheorghe, R

Andruh, M

Costes, JP

Donnadieu, B

机构：

[1] Univ Bucharest, Fac Chem, Inorgan Chem Lab, Bucharest 020464, Romania

[2] CNRS, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse 4, France

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 22期

关键词：

D O I：

10.1039/b310082k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel heterospin system, [{CuL}Gd(H2O)(3)-{Fe(CN)(6)}].4H(2)O, is obtained by reacting the mononuclear complex, [CuL], with gadolinium(III) nitrate, followed by the substitution of the nitrato groups with [Fe(CN)(6)](3-) ions (L2- = N,N'-propylenedi(3 methoxysalicylideneiminato)).

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页码：2778 / 2779

页数：2

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