Micrometer-sized hexagonal tubes self-assembled by a cyclic peptide in a liquid crystal

被引:68
作者
Leclair, S
Baillargeon, P
Skouta, R
Gauthier, D
Zhao, Y [1 ]
Dory, YL
机构
[1] Univ Sherbrooke, Dept Chim, Lab Polymeres & Cristaux Liquides, Sherbrooke, PQ J1K 2R1, Canada
[2] Univ Sherbrooke, Dept Chim, Lab Synth Supramol, Sherbrooke, PQ J1K 2R1, Canada
关键词
liquid crystals; nanostructures; nanotubes; peptides; self-assembly;
D O I
10.1002/anie.200352259
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dissolved in nematic liquid crystals, rigid disk-shaped macrolactams may form large hexagonal hollow tubes. Computer modeling (see picture, O red, N blue, C gray, H white), Raman and infrared microspectroscopy reveal a hierarchical and self-similar-structured self-assembly of the cyclic peptide in the liquid-crystal medium.
引用
收藏
页码:349 / 353
页数:5
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