A New Luminescent Zn(II) Coordination Polymer With Eightfold Interpenetrated ths Topology

被引：2
|
作者：
An, Zhe [1 ]
Zhu, Ling [1 ]
机构：
[1] Guangdong Univ Petrochem Technol, Sch Chem Engn, Maoming, Guangdong, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 09期
关键词：
Zn(II) compound; 2,5-thiophenedicarboxylic acid; interpenetrated framework; luminescence; METAL-ORGANIC FRAMEWORKS; LIGANDS; CONSTRUCTION; NETWORKS;
D O I：
10.1080/15533174.2015.1004462
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Via the solvothermal reactions of Zn(NO3)(2), H(2)tdc and bib, a new Zn(II) coordination polymer, namely [Zn(tdc)(bib) 0.5(H2O)] n (1 H(2)tdc D 2,5-thiophenedicarboxylic acid, bib D 1,4-bis(imidazolyl) butane), was obtained. The crystal crystallizes in orthorhombic Pbcn space group, a = 11.6785(4) angstrom, b = 11.6776(6) angstrom, c = 19.8439(7) angstrom, alpha = b = gamma D 90 degrees, Z = 8. The single X-ray structural analysis reveals that compound 1 features a 8-fold interpenetrated 3D framework with 3-connected ths topology. In addition, the solid state luminescent property of 1 was also investigated at room temperature.
引用
收藏
页码：1367 / 1370
页数：4
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