Catalytic functionality of unsupported molybdenum sulfide catalysts prepared with different methods

被引：84

作者：

Iwata, Y

Sato, K

Yoneda, T

Miki, Y

Sugimoto, Y

Nishijima, A

Shimada, H

机构：

[1] Petr Energy Ctr KSP R&D, Adv Catalysts Res Lab, Kanagawa 213, Japan

[2] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 305, Japan

来源：

CATALYSIS TODAY | 1998年 / 45卷 / 1-4期

关键词：

hydrogenation; hydrosulfurization; XRD; TEM; MoS2; structure; active sites;

D O I：

10.1016/S0920-5861(98)00262-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The catalytic functionality and structural properties of three kinds of unsupported molybdenum sulfide catalysts were investigated by model test reactions and BET, TEM, XPS and XRD analyses. The results indicated that highly bent multilayered MoS2 structures were more catalytically active, while a well crystallized MoS2 structure was more favorable for direct S-extrusion during the reactions of dibenzothiophene. It was proposed that the curvature of MoS2 basal planes was catalytically active, though they were less active for hydrodesulfurization than the edge planes. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：353 / 359

页数：7

共 17 条

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