Unsymmetrical 1,1-Bisboryl Species: Valuable Building Blocks in Synthesis

被引：25

作者：

Babu, K. Naresh ^{[1
]}

Massarwe, Fedaa ^{[1
]}

Reddy, Reddy Rajasekhar ^{[1
]}

Eghbarieh, Nadim ^{[1
]}

Jakob, Manuella ^{[1
]}

Masarwa, Ahmad ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Inst Chem, Edmond J Safra Campus, IL-9190401 Jerusalem, Israel

来源：

MOLECULES | 2020年 / 25卷 / 04期

关键词：

1,1-bis(boryl)alkanes and alkenes; bismetallated organic compounds; Suzuki-Miyaura cross-coupling; chemoselective transformations; CROSS-COUPLING REACTION; ALKYNES; BORON; ACID; DIBORATION; BORYLATION; HYDROBORATION; ACTIVATION; DISCOVERY; REAGENTS;

D O I：

10.3390/molecules25040959

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.

引用

页数：30