Catena-poly[{di-mu-nitrato-1:2 kappa O-4-bis[(triphenylphosphine-P)copper(I)]}-mu-4,4'-bipyridyl-N:N'] tetrahydrofuran solvate

被引：13
|
作者：
Prest, PJ
Moore, JS
机构：
[1] UNIV ILLINOIS, DEPT MAT SCI & ENGN, URBANA, IL 61801 USA
[2] UNIV ILLINOIS, BECKMAN INST ADV SCI & TECHNOL, URBANA, IL 61801 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1996年 / 52卷
关键词：
D O I：
10.1107/S0108270196006087
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A copper(I) complex with triphenylphosphine and 4,4'-bipyridine results in a one-dimensional polymer, {[Cu-2(NO3)(2)(C18H15P)(2)(C10H8N2)].2C(4)H(8)O}(n). The Cu centers are alternately bridged by nitrate counterions and bipyridine ligands. The four-membered Cu2O2 ring lies on an inversion center (1/2 - x, 1/2 - y, - z) and the bipyridyl ligand lies on another inversion center (1/2 - x, 3/2 - y, - z). The triphenylphosphine ligand coordinates to copper providing a distorted tetrahedral coordination environment, with bond lengths Cu1-P 2.168 (1), Cu-N 2.013 (3) and Cu-O 2.177 (2) and 2.147 (2) Angstrom. The cavities between the chains contain tetrahydrofuran solvent molecules.
引用
收藏
页码：2176 / 2178
页数：3
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