Creation of a monomeric ruthenium species on the surface of micro-size copper hydrogen phosphate: An active heterogeneous catalyst for selective aerobic oxidation of alcohols

被引：11

作者：

Liu, Junhua

Wang, Fang

Sun, Kunpeng

Xu, Xianlun ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 16期

关键词：

alcohols; aldehydes; copper hydrogen phosphate; ketones; oxidation; ruthenium;

D O I：

10.1002/adsc.200700187

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new micro-size copper hydrogen phosphate (CHP) synthesized by the emulsion method combined with a monomeric ruthenium species was found to be a very effective catalyst for the selective oxidation of alcohols. Several kinds of alcohols were transformed into the corresponding aldehydes or ketones over the RuCHP catalyst by oxygen under very mild conditions. The results showed that the CHP material was perfect as a catalyst support due to its high ion-exchange ability and adsorption capacity.

引用

页码：2439 / 2444

页数：6

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