Experimental investigation of the Al-Ce-Nd system

被引：8

作者：

Cardinale, AM ^{[1
]}

Cacciamani, G ^{[1
]}

Borzone, G ^{[1
]}

Ferro, R ^{[1
]}

机构：

[1] Univ Genoa, Dipartimento Chim & Chim Ind, I-16146 Genoa, Italy

来源：

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY | 2003年 / 27卷 / 02期

关键词：

D O I：

10.1016/j.calphad.2003.07.002

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In the framework of a systematic investigation of intermetallic systems including rare earths and aluminum, Ce-Nd-Al alloys have recently been investigated by x-ray diffraction, optical microscopy, scanning electron microscopy and electron probe microanalysis. In particular, the Ce-Nd-Al isothermal section at 500 degreesC has been experimentally determined. This section is characterized by several line compounds extending from the binary R-Al subsystems into the ternary field. Complete solid solutions are found in the ternary system when the Ce-Al and the corresponding Nd-Al compounds are isostructural (CeAl3 and NdAl3, CeAl2 and NdAl. The remaining binary phases show lower ternary solubilities. These results have been used together with the thermodynamic data available in literature on the binary subsystems for a thermodynamic modeling and optimization of the Ce-Nd-Al system, by means of the CALPHAD method (Calphad (this issue)). (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：221 / 226

页数：6

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