Microgel-stabilized metal nanoclusters: Improved solid-state stability and catalytic activity in Suzuki couplings

被引：50

作者：

Biffis, A ^{[1
]}

Sperotto, E ^{[1
]}

机构：

[1] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy

来源：

LANGMUIR | 2003年 / 19卷 / 22期

关键词：

D O I：

10.1021/la0350709

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A report on the novel class of microgel-stabilized metal nanoclusters with improved stability in the solid state and on their catalytic activity in Suzuki coupling reactions was presented. The average size and size distribution of the microgel-stabilized metal nanoclusters were investigated by transmission electron microscopy (TEM). The unreduced palladium precursors were significantly more active than the corresponding nanoclusters.

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页码：9548 / 9550

页数：3

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