Infrared rigidochromism: A new effect in the IR spectra of the excited states of coordination compounds

被引：32

作者：

Clark, IP ^{[1
]}

George, MW ^{[1
]}

Johnson, FPA ^{[1
]}

Turner, JJ ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 13期

关键词：

D O I：

10.1039/cc9960001587

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The magnitude of the shift in the nu(CO) IR spectrum of the MLCT excited state of [Re(CO)(3)Cl(bipy)] (bipy = 2,2'-bipyridyl) in PrCN-EtCN solution, compared with the ground-state spectrum, decreases on cooling from fluid to glass; this 'infrared rigidochromic' effect is explained by the change in character of the MLCT state on glass formation.

引用

页码：1587 / 1588

页数：2

共 17 条

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