Facile one-pot synthesis of NiCo2Se4-rGO on Ni foam for high performance hybrid supercapacitors

被引:31
作者
Amin, Bahareh Golrokh [1 ]
Masud, Jahangir [1 ]
Nath, Manashi [1 ]
机构
[1] Missouri Univ Sci & Technol, Dept Chem, Rolla, MO 65409 USA
关键词
REDUCED GRAPHENE OXIDE; ASYMMETRIC SUPERCAPACITORS; SOLVOTHERMAL SYNTHESIS; HYDROTHERMAL SYNTHESIS; ELECTRODE MATERIAL; CARBON NANOSHEETS; NISE2; NANOSTRUCTURES; CAPACITANCE; COMPOSITES;
D O I
10.1039/c9ra06439g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile, innovative synthesis for the fabrication of NiCo2Se4-rGO on a Ni foam nanocomposite via a simple hydrothermal reaction is proposed. The as-prepared NiCo2Se4-rGO@Ni foam electrode was tested through pxrd, TEM, SEM, and EDS to characterize the morphology and the purity of the material. The bimetallic electrode exhibited outstanding electrochemical performance with a high specific capacitance of 2038.55 F g(-1) at 1 A g(-1). NiCo2Se4-rGO@Ni foam exhibits an extensive cycling stability after 1000 cycles by retaining 90% of its initial capacity. A superior energy density of 67.01 W h kg(-1) along with a high power density of 903.61 W kg(-1) further proved the high performance of this electrode towards hybrid supercapacitors. The excellent electrochemical performance of NiCo2Se4-rGO@Ni foam can be explained through the high electrocatalytic activity of NiCo2Se4 in combination with reduced graphene oxide which increases conductivity and surface area of the electrode. This study proved that NiCo2Se4-rGO@Ni foam can be utilized as a high energy density-high power density electrode in energy storage applications.
引用
收藏
页码:37939 / 37946
页数:8
相关论文
共 62 条
[1]   Ultrasensitive and Highly Selective Ni3Te2 as a Nonenzymatic Glucose Sensor at Extremely Low Working Potential [J].
Amin, Bahareh Golrokh ;
De Silva, Umanga ;
Masud, Jahangir ;
Nath, Manashi .
ACS OMEGA, 2019, 4 (06) :11152-11162
[2]   A non-enzymatic glucose sensor based on a CoNi2Se4/rGO nanocomposite with ultrahigh sensitivity at low working potential [J].
Amin, Bahareh Golrokh ;
Masud, Jahangir ;
Nath, Manashi .
JOURNAL OF MATERIALS CHEMISTRY B, 2019, 7 (14) :2338-2348
[3]   CoNi2Se4 as an efficient bifunctional electrocatalyst for overall water splitting [J].
Amin, Bahareh Golrokh ;
Swesi, Abdurazag T. ;
Masud, Jahangir ;
Nath, Manashi .
CHEMICAL COMMUNICATIONS, 2017, 53 (39) :5412-5415
[4]   Facile hydrothermal synthesis of hexapod-like two dimensional dichalcogenide NiSe2 for supercapacitor [J].
Arul, Narayanasamy Sabari ;
Han, Jeong In .
MATERIALS LETTERS, 2016, 181 :345-349
[5]   Electrodeposited NiSe2 on carbon fiber cloth as a flexible electrode for high-performance supercapacitors [J].
Bao, Quanlin ;
Wu, Jihuai ;
Fan, Leqing ;
Ge, Jinhua ;
Dong, Jia ;
Jia, Jinbiao ;
Zeng, Jiali ;
Lin, Jianming .
JOURNAL OF ENERGY CHEMISTRY, 2017, 26 (06) :1252-1259
[6]   Phase Exploration and Identification of Multinary Transition-Metal Selenides as High-Efficiency Oxygen Evolution Electrocatalysts through Combinatorial Electrodeposition [J].
Cao, Xi ;
Hong, Yu ;
Zhang, Ning ;
Chen, Qingzhi ;
Masud, Jahangir ;
Zaeem, Mohsen Asle ;
Nath, Manashi .
ACS CATALYSIS, 2018, 8 (09) :8273-8289
[7]   Activated porous carbon prepared from paulownia flower for high performance supercapacitor electrodes [J].
Chang, Jiuli ;
Gao, Zhiyong ;
Wang, Xiaorui ;
Wu, Dapeng ;
Xu, Fang ;
Wang, Xin ;
Guo, Yuming ;
Jiang, Kai .
ELECTROCHIMICA ACTA, 2015, 157 :290-298
[8]   Bimetallic nickel cobalt selenides: a new kind of electroactive material for high-power energy storage [J].
Chen, Haichao ;
Chen, Si ;
Fan, Meidiang ;
Li, Chao ;
Chen, Da ;
Tian, Guanglei ;
Shu, Kangying .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (47) :23653-23659
[9]   Biomass based N-doped hierarchical porous carbon nanosheets for all-solid-state supercapacitors [J].
Chen, Mingfeng ;
Yu, Dan ;
Zheng, Xiaozhong ;
Dong, Xiaoping .
JOURNAL OF ENERGY STORAGE, 2019, 21 :105-112
[10]   One-Step Solvothermal Synthesis of 3D Hierarchical NixCo9-xS8 Structures for High-Performance Supercapacitors [J].
Chen, Rongna ;
Liu, Lei ;
Hou, Li ;
Zhou, Junshuang ;
Gao, Faming .
CHEMELECTROCHEM, 2017, 4 (09) :2250-2259