A simple method for the α-oxygenation of aldehydes

被引：27
作者：
Beshara, CS
Hall, A
Jenkins, RL
Jones, TC
Parry, RT
Thomas, SP
Tomkinson, NCO
机构：
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3TB, S Glam, Wales
[2] GlaxoSmithKline Pharmaceut, Neurol & GI Ctr Excellence Drug Discovery, Harlow CM19 5AW, Essex, England
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 11期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1039/b418101h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mild, efficient and general method for the chemospecific alpha-oxygenation of aldehydes is described. Treatment of a series of aldehydes with N-tert-butyl-O-benzoyl hydroxylamine hydrochloride gives the corresponding alpha-oxygenated carbonyl via a proposed pericyclic rearrangement process.
引用
收藏
页码：1478 / 1480
页数：3
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