Pd(OH)2/C-mediated selective oxidation of silyl enol ethers by tert-butylhydroperoxide, a useful method for the conversion of ketones to α,β-enones or β-silyloxy-α,β-enones

被引：78

作者：

Yu, JQ ^{[1
]}

Wu, HC

Corey, EJ

机构：

[1] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

[2] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA USA

[3] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 07期

关键词：

D O I：

10.1021/ol050284y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pd(OH)(2)-catalyzed oxidation of silyl enol ethers by t-BuOOH gives either beta-silyloxy-alpha,beta-enones or alpha,beta-enones in good yields depending on the base used.

引用

页码：1415 / 1417

页数：3

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