Hydrogen bonding and conformation of 5-substituted dipyrromethanes - A solid state study

被引:0
作者
Senge, MO [1 ]
机构
[1] Trinity Coll Dublin, Dept Chem, Dublin 2, Ireland
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A crystallographic study of nine different meso-substituted dipyrromethanes identifies the main types of intra- and intermolecular hydrogen bonding pattern in this class of porphyrin building blocks. Most compounds form similar hydrogen-bonded dimers in the crystal but distinct differences in the dipyrromethane conformations are observed in dependence on the type of the meso substituent.
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页码:797 / 808
页数:12
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