Kinetically Controlled Synthesis of PdNi Bimetallic Porous Nanostructures with Enhanced Electrocatalytic Activity

被引:141
作者
Zhu, Chengzhou [1 ]
Wen, Dan [1 ]
Oschatz, Martin [2 ]
Holzschuh, Matthias [3 ]
Liu, Wei [1 ]
Herrmann, Anne-Kristin [1 ]
Simon, Frank [3 ]
Kaskel, Stefan [2 ]
Eychmueller, Alexander [1 ]
机构
[1] Tech Univ Dresden, Phys Chem, D-01062 Dresden, Germany
[2] Tech Univ Dresden, Inorgan Chem, D-01062 Dresden, Germany
[3] Leibniz Inst Polymer Res Dresden, D-01069 Dresden, Germany
关键词
FORMIC-ACID ELECTROOXIDATION; OXYGEN-REDUCTION REACTION; METHANOL ELECTROOXIDATION; ALKALINE-MEDIUM; FUEL-CELLS; ALLOY; NANOPARTICLES; PERFORMANCE; CATALYSTS; ETHANOL;
D O I
10.1002/smll.201401432
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A class of 3D PdNi bimetallic nanomaterials with porous nanostructures is synthesized using a facile and versatile approach at room temperature. Due to their porous nanostructures, their clean surfaces, as well as the synergistic effect between their compositions, the as-prepared PdNi exhibit greatly enhanced activity and stability towards methanol electrooxidation in an alkaline medium, holding great promise in fuel cells. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1430 / 1434
页数:5
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