Bis(cyanato-κN)bis(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-κN3)zinc

被引:6
作者
Caballero, Ana B. [1 ]
Quiros, Miguel [1 ]
Rodriguez-Dieguez, Antonio [1 ]
Salas, Juan M. [1 ]
机构
[1] Univ Granada, Fac Ciencias, Dept Quim Inorgan, E-18071 Granada, Spain
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
COMPLEXES;
D O I
10.1107/S1600536811005769
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Zn(NCO)(2)(C7H8N4)(2)], the Zn-II ion exhibits a distorted tetrahedral coordination geometry. The coordination environment is formed by two 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (dmtp) ligands, coordinated through the N atom in position 3, and two cyanate anions interacting by their N atoms. Supramolecular dimers are generated by stacking interactions between the pyrimidine rings of two ligands related by an inversion center [centroid-centroid distance = 3.5444 (18) angstrom].
引用
收藏
页码:M345 / U613
页数:10
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