Characterization of recharge processes in shallow and deeper aquifers using isotopic signatures and geochemical behavior of groundwater in an arsenic-enriched part of the Ganga Plain

Arsenic concentrations in groundwater extracted from shallow aquifers in some areas of the Ganga Plain in the states of Bihar and Uttar Pradesh, exceed 50 mu g L-1 and locally reach levels in the 400 mu g L-1 range. The study covered 535 km(2) of active flood plain of the River Ganga, in Bihar where a two-tier aquifer system has been delineated in a multi-cyclic sequence of Quaternary sand, clay, sandy clay and silty clay all <=similar to 250 m below ground surface. The research used isotopic signatures (delta O-18, delta H-2, H-3, C-14) and major chemical constituents (HCO3-, SO42-, NO3-, Cl-, Ca2+, Mg2+, Na+, K+, As-total) of groundwater to understand the recharge processes and groundwater circulation in the aquifers. Values of delta O-18 and delta H-2 combined with H-3 data indicate that the recharge to the As-enriched top 40 m of the deposits is modern (<50 a), predominantly meteoric, with some evaporation during infiltration, and partly from tanks and other surface water bodies. The lower part of the upper aquifer is vulnerable to mobilization of As with increasing groundwater extraction. The low As lower aquifer (max. 5 mu g L-1) is hydrologically isolated from the upper aquifer and is characterized by lower C-14 concentration and lower (more negative) delta O-18 values. Groundwater in the lower aquifer is similar to 3 ka old, occurs under semi-confined to confined conditions, with hydrostatic head at 1.10 m above the head of the upper aquifer during the pre-monsoon. The recharge areas of the lower aquifer lies in Pleistocene deposits in basin margin areas with the exposed Vindhyan System, at about 55 km south of the area. (C) 2011 Elsevier Ltd. All rights reserved.