New d10 heterometallic coordination polymers based on compartmental Schiff-base ligands. Synthesis, structure and luminescence

被引：21

作者：

Marinescu, Gabriela ^{[1
,2
]}

Madalan, Augustin M. ^{[2
]}

Tiseanu, Carmen ^{[3
]}

Andruh, Marius ^{[2
]}

机构：

[1] Romanian Acad, Coordinat Chem Lab, Inst Phys Chem, Bucharest 060021, Romania

[2] Univ Bucharest, Fac Chem, Inorgan Chem Lab, Bucharest 020464, Romania

[3] Natl Inst Laser Plasma & Radiat Phys, Lab Solid State Quantum Elect, Magurele 077125, Romania

来源：

POLYHEDRON | 2011年 / 30卷 / 06期

关键词：

Heterometallic complexes; Zinc complexes; Silver complexes; Gold complexes; Schiff base ligands; Luminescence; TETRANUCLEAR COPPER(II) COMPLEXES; CRYSTAL-STRUCTURES; BINUCLEAR COMPLEXES; ZINC(II) COMPLEXES; EXO-BIDENTATE; NODES; FLUORESCENCE; DIVERSITY; TECTONS; SYSTEMS;

D O I：

10.1016/j.poly.2011.01.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The self-assembly processes between binuclear[Zn2Ln](2+) complex cations and complex anions, [M(CN)(2)]M-(I) = Ag(I), Au(I)], generate new one-dimensional (1-D) coordination polymers: (1)(infinity)[{(LZn2)-Zn-1(mu(3)-OH)}(2)(H2O){mu- [Ag(CN)(2)]}](ClO4)(3) THF 0.5MeOH (1)(infinity)[{(LZn2)-Zn-1(mu(3)-OH)}(2)(H2O){mu- [Au(CN)(2)]}](ClO4)(3) THE H2O 2, (1)(infinity)[{(LZn2)-Zn-2(mu-OH)}{mu-[ Ag(CN)(2)]}[Ag(CN)(2)] H2O 3 (H2Ln are bicompartmental Schiff-base ligands resulting from condensation reactions between 2,6-diformyl-p-cresol with 2-aminomethyl-pyridine, and 2-aminoethyl-pyridine, respectively). The luminescence properties of the new heterometallic complexes have been investigated. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：1070 / 1075

页数：6

共 57 条

[1] Photofunctional supramolecular solution systems of chiral Schiff base nickel(II), copper(II), and zinc(II) complexes and photochromic azobenzenes [J].

Akitsu, Takashiro .

POLYHEDRON, 2007, 26 (12) :2527-2535

[2] Synthesis and characterization of mono- and bis-ligand zinc(II) and cadmium(II) complexes of the di-2-pyridylketone Schiff base of S-benzyl dithiocarbazate (Hdpksbz) and the X-ray crystal structures of the [Zn(dpksbz)2] and [Cd(dpksbz)NCS]2 complexes [J].

Ali, MA ;

Mirza, AH ;

Nazimuddin, M ;

Ahmed, R ;

Gahan, LR ;

Bernhardt, PV .

POLYHEDRON, 2003, 22 (11) :1471-1479

[3] Binuclear complexes as tectons in designing supramolecular solid-state architectures [J].

Andruh, M .

PURE AND APPLIED CHEMISTRY, 2005, 77 (10) :1685-1706

[4]

Andruh M., 2005, Focus on Organometallic Chemistry Research, P144

[5] Oligonuclear complexes as tectons in crystal engineering: structural diversity and magnetic properties [J].

Andruh, Marius .

CHEMICAL COMMUNICATIONS, 2007, (25) :2565-2577

[6] Crystal engineering of hybrid inorganic-organic systems based upon complexes with dissymmetric compartmental ligands [J].

Andruh, Marius ;

Branzea, Diana G. ;

Gheorghe, Ruxandra ;

Madalan, Augustin M. .

CRYSTENGCOMM, 2009, 11 (12) :2571-2584

[7] Schiff-base compartmental macrocyclic complexes [J].

Atkins, AJ ;

Black, D ;

Blake, AJ ;

MarinBecerra, A ;

Parsons, S ;

RuizRamirez, L ;

Schroder, M .

CHEMICAL COMMUNICATIONS, 1996, (04) :457-464

[8] Artificial molecular-level machines: Which energy to make them work? [J].

Ballardini, R ;

Balzani, V ;

Credi, A ;

Gandolfi, MT ;

Venturi, M .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (06) :445-455

[9] Three new pseudohalide bridged dinuclear Zn(II) Schiff base complexes: Synthesis, crystal structures and fluorescence studies [J].

Basak, Subhra ;

Sen, Soma ;

Banerjee, Sambuddha ;

Mitra, Samiran ;

Rosair, Georgina ;

Rodriguez, M. T. Garland .

POLYHEDRON, 2007, 26 (17) :5104-5112

[10] Inorganic crystal engineering: a personal perspective [J].

Braga, D .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3705-3713

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